Intercalation: how the cell actually works
A lithium-ion cell runs on intercalation: lithium ions shuttle between two electrodes through an electrolyte while electrons flow through an external circuit to power the motor. The cathode is a metal oxide such as NMC (LiNi₀.₈Mn₀.₁Co₀.₁O₂), which stores lithium ions in its crystal lattice during charge; the anode is graphite (LiC₆), where lithium ions slot between graphene layers. On discharge, the anode reaction LiC₆ → C₆ + Li⁺ + e⁻ releases both the ion and the electron that will do useful work. Cell voltage runs 3.0-4.2 V depending on chemistry and state of charge, and packs are typically cycled between 10-90% SoC to protect longevity.
The energy density gap
Petrol carries roughly 12,700 Wh/kg, and even after a ~30% engine efficiency penalty it still delivers about 3,800 Wh/kg of useful energy. A good lithium-ion cell manages 250 Wh/kg, and after a 90% motor efficiency and the weight of cooling, casing and battery management at the pack level, that becomes roughly 160 Wh/kg — around 20-25× less than petrol, useful-energy for useful-energy. That gap is exactly why a 60 kWh pack ends up weighing ~475 kg (cells plus housing) against ~4 kg of petrol carrying the same energy, and why aerodynamics and rolling resistance matter far more for EVs than for combustion cars.
Petrol: 12,700 Wh/kg × ~30% engine efficiency ≈ 3,800 Wh/kg useful
Li-ion: 250 Wh/kg (cell) × ~90% motor efficiency ≈ 225 Wh/kg useful
Pack level: cells + cooling + BMS + casing → ~60–65% of cell energy
250 Wh/kg cell → ~160 Wh/kg pack
C-rates, fast charging and lithium plating
Charge speed is expressed as a C-rate: 1C fills the full capacity in an hour, 2C in 30 minutes, 4C in 15 minutes. Home AC charging runs around 0.1C, while 150-350 kW DC fast chargers push 2-3.5C peak. The limiting factor is lithium plating: at high C-rates, Li⁺ ions arrive at the graphite anode faster than they can intercalate, so excess lithium deposits as metallic lithium on the surface instead — irreversible capacity loss and, in the worst case, dendrite growth that risks a short circuit. This is why fast-charging curves taper current above roughly 60% state of charge, and why "10-80% in 18 minutes" is advertised rather than "0-100%" — the last 20% takes almost as long as the first 80%.
Why batteries degrade even sitting still
A solid electrolyte interphase (SEI) layer forms on the anode during the very first charge and keeps growing slowly afterwards, consuming cyclable lithium — this alone causes roughly 2-3% capacity loss per year even with zero cycling, known as calendar ageing. Cathode particles crack under the repeated volume changes of cycling (NMC expands about 5% fully charged), exposing fresh surface to side reactions, and electrolyte breaks down above 4.3 V or 60°C. A typical pack still holds ~90% capacity after 5 years and ~85% after 8, the point most manufacturer warranties are pegged to.
Frequently asked questions
Why does fast charging degrade a battery faster than slow charging?
At high C-rates, lithium ions arrive at the graphite anode faster than they can intercalate between the graphene layers. The excess lithium deposits as metallic lithium on the surface instead, causing irreversible capacity loss and, in the worst case, dendrite growth that risks a short circuit.
What is a C-rate?
The C-rate expresses charge or discharge current relative to battery capacity: 1C charges the full capacity in one hour, 2C in 30 minutes, and 4C in 15 minutes. Home AC charging is around 0.1C, while DC fast chargers reach 2-3.5C.
Why do lithium-ion batteries lose capacity over time even when not used?
A solid electrolyte interphase layer forms on the anode during the first charge and continues to grow slowly afterwards, consuming cyclable lithium. This calendar ageing removes roughly 2-3% of capacity per year even with no cycling at all.
Try it live
Everything above runs in your browser — open Li-ion Battery Simulator, press charge or discharge to cycle the cell, and adjust C-rate, temperature and internal resistance to see how they shape capacity fade.
▶ Open Li-ion Battery Simulator