Pulsed NMR Spin Echo

2D twin of the RESONIX PX-90 console: Bloch sphere with isochromat dots, the receiver signal with RF markers, a phase histogram and an echo-amplitude curve.

Presets

Playback

Sample and pulses

A field gradient spreads the precession frequencies (T2* decay); the 180-degree pulse reverses the dephasing, leaving only true T2 loss.

Sequence

Model checks

The science

What is modelled

A cloud of isochromats (spin packets) along the sample axis precesses in the rotating frame. A resonant RF field B1 rotates them about the x axis; field inhomogeneity (a gradient) gives each packet a different offset frequency; T1 and T2 relax them. The exact precession-plus-relaxation step is the same module as on the 3D page.

Equations

  • Pulse duration: tp = (θ/360) / (γ B1), γ/2π = 42.577 MHz/T.
  • Free precession of each packet at its offset, Mxy → Mxy e-t/T2, Mz → 1 + (Mz - 1) e-t/T1.
  • Hahn echo at 2τ with amplitude e-2τ/T2.

Checks run in the page

  • A 90-degree pulse gives |Mxy| = 1 and Mz = 0.
  • Homogeneous free decay follows exp(-t/T2).
  • The Hahn echo amplitude follows the T2 prediction.

Classical macroscopic-spin model; uniform B1; not a quantum density-matrix solver. The sample is a finite set of spin packets, so the signal shows small periodic revivals that a continuous distribution would not have.

What to try
  • Press FID with a large gradient: the signal dies in a few milliseconds (T2*), but the Hahn echo recovers it.
  • Detune the RF by 40 Hz and watch the pulse stop being a clean 90 degrees.
  • Shorten T2 to 60 ms and compare the echo curve with exp(-2 tau/T2).
Mx, My and Mz against time
Transverse signal and the T2 envelope
Phase distribution of the spins now
Echo amplitude against delay tau
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