A single-wall carbon nanotube is a graphene honeycomb sheet rolled up
so that one lattice point maps onto another. The vector connecting those
two points is the chiral vector Ch = nยทa1 + mยทa2,
and it fixes everything about the tube's geometry and electronics.
d = aยทโ(nยฒ+nm+mยฒ) / ฯ (diameter, a = 0.246 nm)
ฮธ = atan[ โ3ยทm / (2n+m) ] (chiral angle, 0ยฐโ30ยฐ)
metallic if (nโm) mod 3 = 0
semiconducting otherwise
- n, m โ chiral indices: n=m gives an "armchair" tube (always metallic), m=0 gives "zigzag", anything else is "chiral".
- Tube length โ number of hexagon rings modelled, extended live by CVD growth.
- CVD growth โ chemical vapour deposition: carbon feedstock decomposes on a catalyst particle and the tube lengthens one ring at a time, exactly as shown here.
- Electron flow โ toggles a stream of charge carriers along the tube axis, visible only when the (nโm) mod 3 = 0 metallic rule is satisfied in real nanotubes; here it always runs so you can see the transport path, but the readout tells you the true regime.