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🕳️ Kirkendall Effect: Void Formation from Unequal Interdiffusion

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Void Fraction:
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🕳️ Kirkendall Effect: Void Formation from Unequal Interdiffusion

The simulation shows two metals interdiffusing across a shared junction at different intrinsic rates, tracking inert marker-plane drift and the nucleation and growth of Kirkendall voids from condensing excess vacancies.

🔬 What It Demonstrates

The simulation shows two metals interdiffusing across a shared junction at different intrinsic rates, tracking inert marker-plane drift and the nucleation and growth of Kirkendall voids from condensing excess vacancies.

🎮 How to Use

Adjust the relative diffusivity slider for each metal species and the annealing temperature and time controls to see how marker drift speed and void density near the interface respond.

💡 Did You Know?

The same diffusional imbalance that Kirkendall identified as a metallurgical curiosity in 1947 is now deliberately exploited to manufacture hollow nanoparticles for batteries and catalysis, a technique called the nanoscale Kirkendall effect.