A packed bed of encapsulated phase-change-material (PCM) spheres is a real thermal-battery design: hot heat-transfer fluid (HTF) is pumped through the voids between capsules to melt the PCM and store latent heat (charging); later, cold HTF is pumped through to freeze it back and recover that heat (discharging). This is the classic Schumann two-phase packed-bed model.
The bed is discretised into axial layers. Within each layer the fluid reaches local equilibrium quickly (fluid thermal mass ≪ capsule thermal mass), so the fluid temperature leaving a layer follows an effectiveness relation:
T_f,out = T_p + (T_f,in − T_p) · exp(−NTU), NTU = hA / (ṁ c_f)
Each capsule's bulk temperature then evolves from convective exchange with the fluid passing through its layer:
m_p · c_eff(T_p) · dT_p/dt = hA · (T_f,avg − T_p)
The latent heat of fusion L is absorbed over a narrow melting window ΔT around the melting point T_m using the effective-heat-capacity method — a standard way to fold a phase transition into a sensible-heat ODE:
c_eff(T) = c_solid or c_liquid, plus L/ΔT when |T − T_m| < ΔT/2
- Charge / Discharge — sets whether the inlet HTF is hotter or colder than the bed, i.e. whether the bed is melting (storing) or freezing (releasing) the PCM.
- Inlet temperature — the HTF temperature entering the top of the bed.
- Flow rate — raises ṁ and, through a Nusselt-type correlation h ∝ ṁ0.6, the convective coefficient — a faster flow moves the thermocline through the bed faster but with a shallower temperature gradient.
- Thermocline depth — the fraction of the bed's height that has crossed the midpoint between the initial and inlet temperatures; it is the moving boundary between "charged" and "uncharged" capsules.
Real-world relevance: this exact scheme (macro-encapsulated PCM spheres in a packed column) is used in solar-thermal plants, district-heating buffer tanks and building HVAC storage to store several hours of heat in a fraction of the volume a sensible-heat-only tank would need.