A lithium-ion cell stores energy by moving LiβΊ ions between two
host materials: graphite at the anode and a layered oxide at the
cathode. Charging drives ions (and their paired electrons, via the
external circuit) from cathode to anode against the cell's own
voltage; discharging lets them flow back down that gradient through
the electrolyte, doing useful work on the way.
flux β C-rate Γ conductivity(T, electrolyte)
V_cell β V_cathode β V_anode β IΒ·R_internal
capacity(mAh) = β« I dt
- C-rate β how fast the cell is charged/discharged; 1C fully cycles capacity in one hour.
- Electrolyte conductivity β how freely ions cross the separator; low conductivity throttles flux and raises internal loss.
- Temperature β ion mobility falls sharply in the cold, raising internal resistance.
- Cathode material β NMC, LFP and LCO trade off voltage, capacity and thermal stability.