Collision theory says a chemical reaction only happens when reactant molecules collide with enough kinetic energy to break existing bonds and reach the transition state — the energy barrier called the activation energy (Ea). Most collisions in a gas or liquid are gentle glancing bounces that fail to clear this barrier; only the energetic minority in the high-speed tail of the molecular speed distribution react.
A 10°C rise in temperature roughly doubles many reaction rates near room temperature — not because molecules collide much more often, but because a much larger fraction of collisions now carry enough energy to clear Ea, exactly as predicted by the Arrhenius equation.
A 3D box of molecules bouncing at speeds set by temperature — each collision is checked against an activation-energy barrier, and only the energetic minority flash gold and "react" while the rest just bounce off.
Only collisions whose kinetic energy along the line of centres clears the activation energy Ea can react. Raising temperature widens the speed distribution and pushes more collisions over the barrier, without much changing the collision frequency itself.
Adjust temperature, concentration and Ea, and toggle a catalyst to open a lower-energy pathway. Watch the live energy diagram plot each collision as a green (success) or red (failed) dot against the Ea line.
The Arrhenius equation shows reaction rate depends exponentially on -Ea/RT — which is why a modest temperature rise can double or triple a reaction rate even though average molecular speed barely changes.